Product ID:00194 P-NITROTOLUENE
MSDS Date:01/01/1987
FSC:6665
NIIN:01-288-6773
MSDS Number: BRPHM

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 716-477-3194

Cage: 19139

ION TRACK INSTRUMENTS (508-658-3767)

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 55503

P-NITROTOLUENE (SARA III)

CAS: 99-99-0

RTECS: XT3325000

Fraction By Weight: CA. 100%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 2 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:HMIS: LD50 (ORAL RAT) IS 1960 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED OR
ABSORBED THROUGH THE SKIN. MAY CAUSE TRANSIENT EYE IRRITATION.
Explanation of Carcinogenicity:MFR LISTED NO INFORMATION ABOUT THE
CARCINOGENICITY OF THIS MATERIAL. HMIS DOES NOT EXPECT IT TO BE
CARCINOGENIC.
Effects of Overexposure:P-NITROTOLUENE IN THE BODY FORMS METHEMOGLOBIN,
WHICH IS SUFFICIENT CONCENTRATION CAUSES CYANOSIS.
Medical Cond Aggravated by Exposure:NO INFORMATION GIVEN ON MSDS BY
MFR.

First Aid:EYE:IMMEDIATELY FLUSH W/WATER & INDUCE VOMITING. GET MEDICAL
ATTENTION. SKIN:IMMEDIATELY FLUSH W/WATER FOR 15 MIN. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. INHALED:REMOVE TO FRESH AIR. GET
MEDICAL AT TENTION IF SYMPTOMS OCCUR. INGESTED:DRINK 1-2 GLASES OF
MILK OR WATER & INDUCE VOMITING. GET MEDICAL ATTENTION.

Autoignition Temp:Autoignition Temp Text:536F
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEEP FIRE EXPOSED
CONTAINERS COOL.
Unusual Fire/Explosion Hazard:FIREOR EXCESSSIVE HEAT MAY PRODUCE
HAZARDOUS CECOMPOSITION PRODUCTS. THIS MATERIAL (UNDER PROPER
CONDITIONS) MAY CREATE A DUST EXPLOSION.

Spill Release Procedures:SWEEP UP MATERIAL & PACKAGE FOR SAFE FEED TO
AN INCINERATOR.
Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY MFR.

Handling and Storage Precautions:KEEP FROM CONTACT WITH OXIDIZING
MATERIAL. KEEP CONTAINER TOIGHTLY CLOSED AND AWAY FROM REDUCING
AGENTS, SODIUM, SULFURIC ACID.
Other Precautions:FIURE OR EXCESSIVE HEAT MAY CAUSE EXPLOSIVE
DECOMPOSITIOHN IF CONFINED.

Respiratory Protection:A NIOSH APPROVED DUST RESPIRATOR SHOULD BE WORN
IF NEEDED.
Ventilation:GOOD GENERAL ROOM VENTILATION SHOULD BE USED. LOCAL EXHAUST
MAY BE NEEDED.
Protective Gloves:PROTECTIVE
Eye Protection:SAFETY GLASSES
Other Protective Equipment:PROTECTIVE CLOTHING SHOULD BE WORN.
Work Hygienic Practices:MFR: ? HMIS:USE GOOD CHEMICAL HYGIENE
PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING
OR DRINKING.
Supplemental Safety and Health
KEY2:KT

HCC:T3
NRC/State Lic Num:NONE
Melt/Freeze Pt:M.P/F.P Text:126F,52C
Decomp Temp:Decomp Text:ABOVE 310C
Vapor Pres:NEGLIGIBLE
Spec Gravity:1.10
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:VERY SLIGHTLY SOLUBL
Appearance and Odor:YELLOW SOLID
Percent Volatiles by Volume:NEG

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, REDUCING AGENTS, SODIUM, SULFURIC ACID
Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 210C.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON
DIOXIDE, CARBON MONOXIDE, POSSIBLE NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:DISCHARGE,TREATMENT,OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE & LOCAL LAWS. DISPOSE BY INCINERATION OR CONTRACT
WITH LICENSED CHEMICAL WASTE DISPOSAL AGENCY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.